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Influence of electrode preparation on electrocatalytic activity of water soluble porphyrazine complex to hydrogen
Klusáčková, Monika ; Janda, Pavel ; Tarábková, Hana
The influence of electrode preparation and used electrode substrate on electrocatalytic activity of N, N`,N``,N```tetramethyl-tetra-3,4-pyridinopor-phyrazinocobalt (CoTmt-3,4-ppa) complex deposited on electrode surface for hydrogen reaction has been studied. Electrochemical deposition, spontaneous adsorption, and spin coating have been used to the modification of two different electrode substrates: annealed gold and highly oriented pyrolytic graphite. Prepared electrodes have been characterized using cyclic voltammetry, backscattering VIS spectroscopy and atomic force microscopy. The detailed comparison of surface morphology, surface coverage, surface roughness parameters, and thickness of deposited layers of CoTmt-3,4-ppa mediatoronhydrogen reaction has been investigated.
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Effect of substrate hydrophobicity on the electrocatalytic behaviour of phthalocyanine
Klusáčková, Monika ; Janda, Pavel ; Tarábková, Hana
In this work, the electrocatalytic activity of pyridinoporphyrazine mediator deposited on two substrates with different hydrophobicity has been presented. We focused on hydrophobic highly oriented pyrolytic graphite (HOPG) as well as hydrophilic annealed gold electrode (Au111). The immobilization of mediator has been carried out spontaneous adsorption from aqueous solution on electrode surfaces. The different hydrophobicity surface resulted in change the electrocatalytic activities of mediator to hydrogen in aqueous solution. For this purpose, electrochemical, in situ spectroelectrochemical, and ex situ microscopically characterizations have been performed. The detailed comparison of surface morphology, surface coverage, surface roughness parameters, thickness of deposited layers of mediator, and pH solution has been studied.
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Influence of Electrode Preparation on Electrocatalytic Activity of Tetrapyridinoporphyrazinato Cobalt(II) Complex to Propylene
Klusáčková, Monika ; Janda, Pavel ; Tarábková, Hana
The water-soluble complex N ,N' ,N' ',N' "-Tetramethyl-tetra-3,4-pyridinoporphyrazinocobalt (CoTmt-3,4-ppa) has been deposited by different techniques on two substrate. Electrochemical deposition, spontaneous adsorption, and spin coating have been used to the modification of two electrode material: annealed gold as hydrophilic substrate and highly oriented pyrolytic graphite as hydrophobic substrate. The modified electrodes have been characterized using cyclic voltammetry, backscattering VIS spectroscopy and atomic force microscopy. The influence of substrate material and modification techniques on electrocatalytic activity of CoTmt-3,4-ppa modified electrodes for propylene oxidation has been studied.
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